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Statistical Thermodynamics - Spring 2021


(Statistical Thermodynamics - Spring 2017)
Material covered:

(Syllabus)

Week Monday Wednesday
Feb 1 Methods of Thermodynamics and Statistical Physics. Definitions of thermodynamics. Temperature. Equation of state. Thermodynamic coefficients. Work. Internal energy. First law of thermodynamics. Heat. Heat capacity. Mayer's equation.
Feb 8 The adiabatic equation. Heat machines. Carnot cycle. Entropy at equilibrium. Thermodynamic potentials. Thermodynamic relations. Entropy of the ideal gas. Adiabatic thermodynamic coefficients.
Feb 15 Presidents Day, no classes Problem solving
Feb 22 Third law of thermodynamics. Systems with variable mass, chemical potential. Thermodynamic stability. Second law of thermodynamics. Carnot's theorem.  Entropy increase in irreversible processes.
Mar 1 Molecular theory of the ideal gas. Basic assumptions. Characteristic lengths. Velocity and speed distribution function. Molecular flux. Pressure due to molecular impact. Relation between temperature and average kinetic energy. Heat capacity of the ideal gas. Degrees of freedom. Maxwell-Boltzmann disctribution. Characteristic speeds of molecules.
Mar 8 Midterm test 1 Statistical physics. Classical vs. quantum approaches. Quantum states and equidistribution assumption. Combinatorics and thermodynamic probability. Coin tossing experiment. Stirling formula.
Mar 15 Combinatorics of multistate particles. Degeneracy. Thermodynamic probability and entropy. Boltzmann statistics. Relation between statistical parameters and thermodynamic quantities. Formalism of quantum mechanics. Eigenvalue problems for matrices and differential operators. Stationary Schrödinger equation. Particle in a rigid box. Degeneracy. Density of states.
Mar 22 Statistical thermodynamics of the ideal gas Statistical mechanics of harmonic oscillators
Mar 29 Spring Recess Spring Recess
Apr 5 Average quantum number of the harmonic oscillator as a particular case of the Bose-Einstein distribution. Statistical mechanics of rotators. Problem solving
Apr 12 Solid as a collection of harmonic oscillators. Sound waves in a box. Phonons. Density of states. Heat capacity of solids. Debye theory. Spins in magnetic field. Energy levels and partition function. Brillouin function, heat capacity, and magnetic susceptibility.
Apr 19 Spins in magnetic field. Phase transitions and mean-field approximation. ... Continued. Problem solving.
Apr 26 Grand canonical ensemble for systems of indistinguishable particles and systems with interaction. Spin and statistics. Bosons and fermions. ...Continued.
May 3 Bose condensation. Energy, heat capacity, and pressure of the Bose gas. Fermi gas at zero temperature. Degenerate Fermi gas at nonzero temperatures. Heat capacity of the degenerate Fermi gas
May 10 1D Ising model Midterm test 2
May 17 Problem solving No classes

 
Problem sets:
Problems 01 02 03 04 05
Solutions 01 02 03 04 05

   
Books
 
1. Ashley H. Carter, Classical and Statistical Thermodynamics
2. F. Reif, Statistical Physics

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